World number one Djokovic struck 51 winners to notch up the win against Edmund, extending his unbeaten run this year to 25 matches.
Garcia looked untouchable in the first set and for much of the second, blasting 30 winners and breaking Pliskova's serve three times en route to a 6-1, 7-6 (2) victory.
Germany started brightly on home soil and created the first chance of the game as Toni Kroos' cross into the box allowed Thilo Kehrer to test Spain goalkeeper David de Gea in the 11th minute.
"Our original partnership was mainly focused on the World Cup in China. We are thrilled that this has now expanded to be a more all-encompassing partnership across all FIBA competitions."
The Tour, which was moved from its original date in July due to the COVID-19 pandemic, ends in Paris on September 20. The next stage is a 191km ride from Le Teil to Mont Aigoual. Enditem
"It was a fantastic evening. The conditions, crowd, competition - it was all fabulous. Sam is a fabulous competitor, and I feel we bring the best out of each other," Duplantis added.
Meanwhile United coach Ole Gunnar Solskjaer commented that he was pleased with what the talented playmaker could bring to his team.
A lonely Lutsenko sprinted to the finish and had to wait 55 seconds before the second rider Herrada appeared.
In other matches on Wednesday, Ceara beat local rivals Fortaleza 1-0, Atletico Goianiense drew 1-1 at Fluminense, Corinthians won 2-1 at Goias and Bragantino drew 1-1 at Athletico Paranaense. Enditem
Bayern remains the league's flagship from an international perspective, the official underlined.
The organizers designed a route with a 17km climb before the finish line, which seemed like it might bring about some interesting developments on the rugged, narrow mountain road.